Macroscopic derivation of the kinetic mass-action law
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2010-01-01
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Using several reaction examples with experimentally determined rate equations, traditional mass action rate equations are shown to be simplified forms of polynomial approximation to a general rate function derived by non-equilibrium thermodynamics for a mixture of fluids with linear transport properties. The mass action kinetic law is thus proved also on the macroscopic level and limited to this type of fluids.
Odvození kinetického zákona o působení hmoty metodami nerovnážné termodynamiky kontinua, zavedení nového pojmu termodynamický polynom do kinetiky.
Odvození kinetického zákona o působení hmoty metodami nerovnážné termodynamiky kontinua, zavedení nového pojmu termodynamický polynom do kinetiky.
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Reaction Kinetics, Mechanisms and Catalysis. 2010, vol. 99, issue 1, p. 29-35.
http://link.springer.com/10.1007/s11144-009-0101-6
http://link.springer.com/10.1007/s11144-009-0101-6
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en
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(C) Springer-Verlag