Thermodynamic Driving Forces and Chemical Reaction Fluxes; Reflections on the Steady State

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dc.contributor.authorPekaƙ, Miloslavcs
dc.coverage.issue3cs
dc.coverage.volume25cs
dc.date.accessioned2020-08-04T10:59:31Z
dc.date.available2020-08-04T10:59:31Z
dc.date.issued2020-02-01cs
dc.description.abstractMolar balances of continuous and batch reacting systems with a simple reaction are analyzed from the point of view of finding relationships between the thermodynamic driving force and the chemical reaction rate. Special attention is focused on the steady state, which has been the core subject of previous similar work. It is argued that such relationships should also contain, besides the thermodynamic driving force, a kinetic factor, and are of a specific form for a specific reacting system. More general analysis is provided by means of the non-equilibrium thermodynamics of linear fluid mixtures. Then, the driving force can be expressed either in the Gibbs energy (affinity) form or on the basis of chemical potentials. The relationships can be generally interpreted in terms of force, resistance and flux.en
dc.formattextcs
dc.format.extent1-10cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationMOLECULES. 2020, vol. 25, issue 3, p. 1-10.en
dc.identifier.doi10.3390/molecules25030699cs
dc.identifier.issn1420-3049cs
dc.identifier.other163725cs
dc.identifier.urihttp://hdl.handle.net/11012/188951
dc.language.isoencs
dc.publisherMDPIcs
dc.relation.ispartofMOLECULEScs
dc.relation.urihttps://www.mdpi.com/1420-3049/25/3/699cs
dc.rightsCreative Commons Attribution 4.0 Internationalcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/1420-3049/cs
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/cs
dc.subjectchemical kineticsen
dc.subjectchemical thermodynamicsen
dc.subjectdriving forceen
dc.subjectreaction fluxen
dc.subjectreaction rateen
dc.titleThermodynamic Driving Forces and Chemical Reaction Fluxes; Reflections on the Steady Stateen
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionpublishedVersionen
sync.item.dbidVAV-163725en
sync.item.dbtypeVAVen
sync.item.insts2020.08.04 12:59:31en
sync.item.modts2020.08.04 12:45:19en
thesis.grantorVysokĂ© učenĂ­ technickĂ© v Brně. Fakulta chemickĂĄ. Centrum materiĂĄlovĂ©ho vĂœzkumucs
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