Spin Crossover in Three Mononuclear Iron (III) Schiff Base Complexes

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2019-08-02
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10.3390/met9080849
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Abstract
The synthesis, crystal structure, and magnetic properties of three new mononuclear complexes [Fe(R-LA)(L1)](BPh4), where R-LA(2-) is a doubly deprotonated pentadentate Schiff base ligand and L1 is a monodentate benzimidazole or furopyridine ligand, are reported. Ligand- and anion-driven changes in crystal structures and magnetic behavior were investigated in terms of the magnetic susceptibility measurements and theoretical calculations.
Keywords
spin crossover, Schiff base ligands, iron (III) complex, structure, magnetism
Persistent identifier
http://hdl.handle.net/11012/194809
Document type
Peer reviewed
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Source
Metals. 2019, vol. 9, issue 8, p. 1-11.
https://www.mdpi.com/2075-4701/9/8/849
DOI
10.3390/met9080849
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Creative Commons Attribution 4.0 International
Except where otherwise noted, this item's license is described as Creative Commons Attribution 4.0 International