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Detailed balance in reaction kinetics - consequence of mass conservation?
Detailed balance condition for triangular isomerisation mechanism is derived from the more general permanence of atoms, consequently, it should be viewed as a special equilibrium result of mass conservation.
Macroscopic derivation of the kinetic mass-action law
Using several reaction examples with experimentally determined rate equations, traditional mass action rate equations are shown to be simplified forms of polynomial approximation to a general rate function derived by ...