3D Printing Temperature Tailors Electrical and Electrochemical Properties through Changing Inner Distribution of Graphite/Polymer

dc.contributor.authorIffelsberger, Christiancs
dc.contributor.authorJellett, Cameroncs
dc.contributor.authorPumera, Martincs
dc.coverage.issue24cs
dc.coverage.volume17cs
dc.date.accessioned2021-11-30T15:56:24Z
dc.date.available2021-11-30T15:56:24Z
dc.date.issued2021-06-01cs
dc.description.abstractThe rise of 3D printing technology, with fused deposition modeling as one of the simplest and most widely used techniques, has empowered an increasing interest for composite filaments, providing additional functionality to 3D-printed components. For future applications, like electrochemical energy storage, energy conversion, and sensing, the tuning of the electrochemical properties of the filament and its characterization is of eminent importance to improve the performance of 3D-printed devices. In this work, customized conductive graphite/poly(lactic acid) filament with a percentage of graphite filler close to the conductivity percolation limit is fabricated and 3D-printed into electrochemical devices. Detailed scanning electrochemical microscopy investigations demonstrate that 3D-printing temperature has a dramatic effect on the conductivity and electrochemical performance due to a changed conducive filler/polymer distribution. This may allow, e.g., 3D printing of active/inactive parts of the same structure from the same filament when changing the 3D printing nozzle temperature. These tailored properties can have profound influence on the application of these 3D-printed composites, which can lead to a dramatically different functionality of the final electrical, electrochemical, and energy storage device.en
dc.formattextcs
dc.format.extent1-9cs
dc.format.mimetypeapplication/pdfcs
dc.identifier.citationSmall. 2021, vol. 17, issue 24, p. 1-9.en
dc.identifier.doi10.1002/smll.202101233cs
dc.identifier.issn1613-6829cs
dc.identifier.other172499cs
dc.identifier.urihttp://hdl.handle.net/11012/203021
dc.language.isoencs
dc.publisherWiley-VCHcs
dc.relation.ispartofSmallcs
dc.relation.urihttps://onlinelibrary.wiley.com/doi/10.1002/smll.202101233cs
dc.rightsCreative Commons Attribution-NonCommercial 4.0 Internationalcs
dc.rights.accessopenAccesscs
dc.rights.sherpahttp://www.sherpa.ac.uk/romeo/issn/1613-6829/cs
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/cs
dc.subject3D print filamenten
dc.subjectcompositeen
dc.subjectfused deposition modelingen
dc.subjectscanning electrochemical microscopyen
dc.subjectsubstrate generationen
dc.subjecttip collection modeen
dc.title3D Printing Temperature Tailors Electrical and Electrochemical Properties through Changing Inner Distribution of Graphite/Polymeren
dc.type.driverarticleen
dc.type.statusPeer-revieweden
dc.type.versionpublishedVersionen
sync.item.dbidVAV-172499en
sync.item.dbtypeVAVen
sync.item.insts2021.11.30 16:56:23en
sync.item.modts2021.11.30 16:15:18en
thesis.grantorVysoké učení technické v Brně. Středoevropský technologický institut VUT. Energie budoucnosti a inovacecs
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