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Macroscopic derivation of the kinetic mass-action law
Using several reaction examples with experimentally determined rate equations, traditional mass action rate equations are shown to be simplified forms of polynomial approximation to a general rate function derived by ...
Thermodynamic analysis of chemically reacting mixtures – comparison of first and second order models
Recently, a method based on non-equilibrium continuum thermodynamics which derives thermodynamically consistent reaction rate models together with thermodynamic constraints on their parameters was analyzed using a triangular ...